Name | Ethanephosphonic acid |
Synonyms | ethylphosphonate Ethyl-phosphonate Ethylphosphonic acid ETHYLPHOSPHONIC ACID ETHANEPHOSPHONIC ACID Ethanephosphonic acid 4-Ethylphosphonic Acid Phosphonic acid, P-ethyl- ethoxy(hydroxy)oxophosphonium Ethylphosphonic acid Solution, 100ppm |
CAS | 6779-09-5 |
EINECS | 229-839-2 |
InChI | InChI=1/C2H7O3P/c1-2-6(3,4)5/h2H2,1H3,(H2,3,4,5)/p-2 |
Molecular Formula | C2H7O3P |
Molar Mass | 110.05 |
Melting Point | 61-63 °C (lit.) |
Boling Point | 330-340℃ (8 Torr) |
Flash Point | 111.3°C |
Water Solubility | Soluble in water. |
Solubility | DMSO (Slightly), Methanol (Slightly) |
Vapor Presure | 0.00365mmHg at 25°C |
Appearance | Solid |
Color | Off-White to Pale Yellow |
BRN | 1743032 |
pKa | pK1:2.43;pK2:8.05 (25°C) |
Storage Condition | Hygroscopic, -20°C Freezer, Under inert atmosphere |
Stability | Stable. Incompatible with strong oxidizing agents, strong bases. |
Sensitive | Moisture Sensitive |
Physical and Chemical Properties | This product is a colorless transparent liquid. |
Hazard Symbols | C - Corrosive |
Risk Codes | 34 - Causes burns |
Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 - Take off immediately all contaminated clothing. S28 - After contact with skin, wash immediately with plenty of soap-suds. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) |
UN IDs | UN 3261 8/PG 2 |
WGK Germany | 3 |
Hazard Class | 8 |
Packing Group | III |
Use | The pesticide is used for the synthesis of the fungicide aluminum triethylphosphonate (aluminum ethylphosphonate). |
production method | the preparation method is the reaction of phosphorus trichloride and ethanol in the presence of water, A mixture of diethyl phosphite and monoethyl phosphite was prepared. Ammonia or sodium hydroxide was then added to convert both to salts. This salt is reacted with a slight excess of aluminum sulfate to give the bactericide aluminum triethylphosphonate. Specific Process: alcohol and water are mixed and cooled to about 10 ℃, and phosphorus trichloride is added dropwise under reduced pressure to keep the temperature at about 30 ℃; After the dropwise addition is completed, the mixture is stirred for 15min, then increase the vacuum to 97 ~ 99kPa, with boiling water heated to 80~85 ℃, and then cooled to 5 ℃, neutralized with about 10% ammonia, then add an excess of 5% ammonia water below 30 ℃ (constant concentration); Stop stirring after adding, stand at 40~45 ℃ for 2H, and dehydrate at 87~93kPa, when the liquid temperature reached 80 ° C., the product monoethyl phosphite was obtained. |